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Positive Material Identification (PMI)

 What Is Positive Material Identification?


Positive Material Identification (PMI) is the in-field or laboratory measurement of the elemental composition of metallic components to verify that the material conforms to the specified alloy designation. It is the primary technique for detecting material mix-ups — the inadvertent substitution of a lower-grade or incorrect alloy material for the specified one — which represents one of the most serious and insidious material integrity risks in process plant construction and maintenance.

PMI Technologies We Deploy:

X-Ray Fluorescence (XRF) Portable XRF analysers bombard the material surface with X-rays, exciting elemental fluorescence that is measured to determine the elemental composition of the alloy. XRF is the most widely used field PMI technology — non-destructive, fast, and capable of identifying and quantifying most alloying elements in a matter of seconds. Particularly effective for stainless steels, nickel alloys, titanium alloys, and other corrosion-resistant alloys (CRAs).

Optical Emission Spectrometry (OES) Portable arc/spark OES analysers use an electrical spark to excite elemental emission from the material surface, providing quantitative elemental analysis including carbon content measurement — which XRF cannot reliably quantify. OES is the preferred method where carbon content verification is required, such as distinguishing between carbon steel grades or verifying low-carbon and extra-low-carbon stainless steel grades. 

 Where We Apply PMI


  • Alloy piping circuit verification in Oil & Gas, Petrochemical, and Chemical processing facilities
  • Heat exchanger tube, tubesheet, and shell material verification 
  • Pressure vessel shell, head, and nozzle material confirmation 
  • Weld filler material verification (wire, rod, and electrode identification) 
  • Valve, fitting, and flange material confirmation 
  • Post-maintenance material verification following component replacement 
  • Materials management and traceability programmes during major capital projects  

Applicable Codes and Standards


  • API 578 — Material Verification Program for New and Existing Alloy Piping Systems (the primary industry reference for PMI programmes)
  • ASME B31.3 — Process Piping — material verification requirements
  • ASTM A751 — Standard Test Methods, Practices, and Terminology for Chemical Analysis of Steel Products
  • Client and operator PMI programme specifications
  • Project-specific PMI plans (100% or risk-based sampling)